Основные понятия
Liquid crystal elastomer ribbons with magnetic domains can reversibly aggregate and disassemble in response to a rotating magnetic field, exhibiting emergent collective behaviors and viscoelastic properties that can be tuned by controlling the ribbon shape.
Аннотация
The content describes the development of a system of magnetically active liquid crystal elastomer (LCE) ribbons that can reversibly aggregate and disassemble in response to an external rotating magnetic field. The key highlights are:
The LCE ribbons are fabricated to have a magnetic domain at one end, allowing them to respond to a rotating magnetic field. The ribbons can change shape, exhibiting varying degrees of bending and twisting, depending on the temperature.
When dispersed in a viscous medium and subjected to a rotating magnetic field, the ribbons mechanically interlock and aggregate into larger clusters. The aggregation kinetics and final cluster size are influenced by the ribbon shape, which is controlled by the temperature. Ribbons with moderate curvature at 65°C form the largest aggregates.
A mathematical model is developed to understand the role of topological mechanisms in the aggregation process. The model shows that the shape of the ribbons, specifically the degree of curvature, affects their propensity for entanglement and the size of the final aggregates.
The aggregates formed exhibit viscoelastic solid-like properties, with the storage modulus and yield stress dependent on the ribbon shape. Heating the aggregates increases the bond strength between the ribbons, further enhancing the mechanical properties.
Controlled dissociation of the aggregates can be induced by imparting high rotational kinetic energy to the ribbons through the magnetic field. The dissociation is governed by the ribbon shape and the viscosity of the surrounding medium.
The system demonstrates the ability to create transient, responsive solids from dilute suspensions of mobile, shape-changing polymeric units, exhibiting emergent collective behaviors reminiscent of natural systems. This could enable applications in areas such as soft robotics and injectable biomaterials.
Статистика
The average number of ribbons per cluster after 120 s for θ = 10° ribbons at 65°C is 34 ± 4.
The storage modulus of the aggregates formed from θ = 10° ribbons at 65°C is at least one order of magnitude larger than the controls.
The activation energy for dissociation of aggregates formed at 65°C is 0.76 nJ, and at 90°C is 2.71 nJ.
Цитаты
"Imparting dynamic collective behaviors into synthetic systems may enable a range of potential applications from bio-inspired soft robotics to injectable biomaterials."
"The formed aggregates are shown to exhibit the properties of viscoelastic solids that are able to store and dissipate energy, and the shape of the individual unit is shown to affect both the aggregation dynamics and the properties of the resulting aggregate."